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Homologous Series

A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

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Student-friendly explanation

Members of a homologous series have similar chemical properties because they share the same functional group. Their physical properties show a gradual change as molecular mass increases. This idea helps students organise carbon compounds into families instead of learning them as isolated names.

How to write this in exams

  1. 1

    Start with the exact idea

    A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

  2. 2

    Then show how to use it

    1. Check the functional group. 2. Compare the general formula. 3. See whether successive compounds differ by CH2. 4. Conclude whether they form a homologous series.

  3. 3

    Add one concrete example

    Methanol, ethanol, and propanol form a homologous series because each has the -OH group and each next member differs by CH2.

  4. 4

    Avoid this incomplete answer

    A common wrong answer is to call any set of related compounds a homologous series. Without the CH2 difference and same functional group, the answer is incomplete.

Definition

A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

Example

Methanol, ethanol, and propanol form a homologous series because each has the -OH group and each next member differs by CH2.

Rule to remember

Members of the same homologous series have the same general formula, the same functional group, and a CH2 difference between successive compounds.

Memory hook

Same group, same family, one CH2 more each step.

Examples and method

Worked example

Methane, ethane, and propane belong to the alkane series. Each next member has one extra CH2 unit, so they form a homologous series with similar chemical behaviour.

Method to apply

1. Check the functional group. 2. Compare the general formula. 3. See whether successive compounds differ by CH2. 4. Conclude whether they form a homologous series.

Diagram support

Write three consecutive members vertically to show the CH2 difference clearly, such as CH4, C2H6, and C3H8.

How CBSE asks it

Questions may ask you to identify a series, state the common difference, or explain why members behave similarly.

Avoid common mistakes

Common confusion

Students often think any group of carbon compounds is a homologous series. The same functional group and a fixed difference of CH2 are both required.

Common wrong answer

A common wrong answer is to call any set of related compounds a homologous series. Without the CH2 difference and same functional group, the answer is incomplete.

Exam tip

When comparing two compounds, check the functional group first and then see whether the formulas differ by CH2.

Quick check

What is the common difference between two successive members of a homologous series?

Successive members of a homologous series differ by one CH2 unit. They also have the same functional group and similar chemical properties.

Answer writing and exam use

1-mark answer

A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

2-mark answer

A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group. Members of the same homologous series have the same general formula, the same functional group, and a CH2 difference between successive compounds. Methanol, ethanol, and propanol form a homologous series because each has the -OH group and each next member differs by CH2.

3-mark answer

Members of a homologous series have similar chemical properties because they share the same functional group. Their physical properties show a gradual change as molecular mass increases. This idea helps students organise carbon compounds into families instead of learning them as isolated names. Members of the same homologous series have the same general formula, the same functional group, and a CH2 difference between successive compounds. Methane, ethane, and propane belong to the alkane series. Each next member has one extra CH2 unit, so they form a homologous series with similar chemical behaviour. Questions may ask you to identify a series, state the common difference, or explain why members behave similarly. A common wrong answer is to call any set of related compounds a homologous series. Without the CH2 difference and same functional group, the answer is incomplete.
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