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Homologous Series

A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

In one line: Same group, same family, one CH2 more each step.

Practice This Concept

Understand it

Members of a homologous series have similar chemical properties because they share the same functional group. Their physical properties show a gradual change as molecular mass increases. This idea helps students organise carbon compounds into families instead of learning them as isolated names.

Example

Methanol, ethanol, and propanol form a homologous series because each has the -OH group and each next member differs by CH2.

Rule to remember

Members of the same homologous series have the same general formula, the same functional group, and a CH2 difference between successive compounds.

See it worked out

Follow the example line by line, then use the same method on new questions.

Worked example

  1. 1Methane, ethane, and propane belong to the alkane series.
  2. 2Each next member has one extra CH2 unit, so they form a homologous series with similar chemical behaviour.

Method you can reuse

  1. 1Check the functional group.
  2. 2Compare the general formula.
  3. 3See whether successive compounds differ by CH2.
  4. 4Conclude whether they form a homologous series.

Sketch it in your answer

Write three consecutive members vertically to show the CH2 difference clearly, such as CH4, C2H6, and C3H8.

Check yourself

Answer the question in your head before opening the answer.

Try it yourself

What is the common difference between two successive members of a homologous series?

Think first, then show answer
Successive members of a homologous series differ by one CH2 unit. They also have the same functional group and similar chemical properties.

Common wrong answer

A common wrong answer is to call any set of related compounds a homologous series. Without the CH2 difference and same functional group, the answer is incomplete.

Don't mix this up

Students often think any group of carbon compounds is a homologous series. The same functional group and a fixed difference of CH2 are both required.

Exam tip

When comparing two compounds, check the functional group first and then see whether the formulas differ by CH2.

Write it in the exam

Each point is worth about one mark. Write point 1 for a 1-mark question and keep adding points as the marks go up.

How CBSE asks it

Questions may ask you to identify a series, state the common difference, or explain why members behave similarly.
  1. 1

    Enough for 1 mark

    A homologous series is a family of organic compounds with the same functional group and the same general formula, where successive members differ by a CH2 group.

  2. 2

    Add for 2 marks

    Example: Methanol, ethanol, and propanol form a homologous series because each has the -OH group and each next member differs by CH2.

  3. 3

    Add for 3 marks

    Members of a homologous series have similar chemical properties because they share the same functional group.

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