EMF, Internal Resistance and Terminal Voltage
EMF of a cell is the work done by the source per unit charge in driving charge around the complete circuit. Internal resistance is the opposition to current within the cell, and terminal voltage is the potential difference available across the cell terminals when current flows.
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Student-friendly explanation
A real cell is not an ideal source. It has internal resistance r, so some energy per unit charge is lost inside the cell when current flows. During discharge, terminal voltage V is less than emf ε and is given by V = ε - Ir. During charging, terminal voltage can exceed emf because the external source pushes current into the cell. This distinction is important in practical circuits and numerical problems involving cells.
How to write this in exams
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Start with the exact idea
EMF of a cell is the work done by the source per unit charge in driving charge around the complete circuit. Internal resistance is the opposition to current within the cell, and terminal voltage is the potential difference available across the cell terminals when current flows.
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Then show how to use it
Represent the real cell as ε in series with r. Decide whether the cell is delivering or receiving current. Find total circuit resistance if an external resistor is given. Calculate current. Apply V = ε - Ir for discharge or V = ε + Ir for charging. Include volt and ohm units.
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Add one concrete example
If a cell of emf 2.0 V and internal resistance 0.5 ohm supplies 1.0 A, its terminal voltage is 2.0 - 0.5 = 1.5 V.
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Avoid this incomplete answer
Using V = ε + Ir for a discharging cell gives a terminal voltage greater than the emf, which contradicts energy loss inside the cell.
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Why is the terminal voltage of a discharging cell less than its emf?
The terminal voltage is less than the emf because part of the cell's energy per unit charge is used in overcoming internal resistance. For a discharging cell, this internal drop is Ir, so the terminal voltage is V = ε - Ir.
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