de Broglie Explanation of Bohr Quantisation
de Broglie's explanation says that an electron in a stable Bohr orbit behaves as a matter wave forming a standing wave around the nucleus, so the circumference of the orbit must contain an integral number of wavelengths: 2πr = nλ.
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Student-friendly explanation
If the electron wave does not fit exactly around the orbit, the wave would not join smoothly with itself and the orbit would not be stable. Stable orbits occur only when the circular path length equals a whole number of de Broglie wavelengths. Using λ = h/mv, the condition 2πr = nλ gives mvr = nh/2π, which is Bohr's angular momentum quantisation.
How to write this in exams
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Start with the exact idea
de Broglie's explanation says that an electron in a stable Bohr orbit behaves as a matter wave forming a standing wave around the nucleus, so the circumference of the orbit must contain an integral number of wavelengths: 2πr = nλ.
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Then show how to use it
Step 1: State that electron has de Broglie wavelength λ = h/mv. Step 2: State stable orbit condition 2πr = nλ. Step 3: Substitute λ. Step 4: Rearrange carefully to get mvr = nh/2π. Step 5: Explain that n must be an integer for a standing wave.
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Add one concrete example
For the first Bohr orbit, n = 1, so the circumference contains one complete de Broglie wavelength. For n = 2, it contains two complete wavelengths.
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Avoid this incomplete answer
A common wrong answer is saying quantisation happens because the electron's speed is zero in a stationary orbit. Stationary orbit means fixed allowed energy, not a stationary electron.
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How does de Broglie's idea justify Bohr's quantisation condition?
de Broglie's idea treats the electron as a matter wave. A stable orbit is possible only when the electron wave forms a standing wave around the orbit, so 2πr = nλ. Substituting λ = h/mv gives mvr = nh/2π, which is Bohr's angular momentum quantisation.
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